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2005
Hydrosilylation
O 0278
Hydrosilylation of (Hetero)-Aromatic Aldimines in the Presence of a Pd(I)
— The reaction of heterocyclic and aromatic azomethines with triethylsilane
10- 040 Complex.
catalyzed by Pd2Cl 2(allyl) 2 is studied. Depending on the nature of the functional groups
in the aza and methin parts of the aldimine molecules, the aromatic amine and C- or
N-silylated products are obtained in different ratios. The reactivity of a series of imines
is compared with their electronic and structural characteristics, determined by quantum-chemical methods (some yields not given). — (IOVEL, I.; GOLOMBA, L.;
FLEISHER, M.; POPELIS, J.; GRINBERGA, S.; LUKEVICS, E.; Chem.
Heterocycl. Compd. (N. Y.) 40 (2004) 6, 701-714; Latv. Inst. Org. Synth., Riga 1006,
Latvia; Eng.) — Bartels
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