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2005
Fused pyrrole derivatives
R 0160
Intermolecular Coupling Reaction of Cyclic Amines and Alkenes Catalyzed by a
Complex (PCy3)2(CO)RuHCl. — The title complex is found to
10- 117 Ruthenium-Hydride
be an efficient catalyst for the reaction of unprotected cyclic amines with unactivated
alkenes. Synthetically useful α-substituted cyclic imines and amines are obtained. In
contrast, the reaction of cyclic amines with vinylsilanes affords N-silylated products.
— (YI*, C. S.; YUN, S. Y.; GUZEI, I. A.; Organometallics 23 (2004) 23, 5392-5395;
Dep. Chem., Marquette Univ., Milwaukee, WI 53233, USA; Eng.) — Klein
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