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2005
Triazole derivatives
R 0280
A Microwave-Assisted Click Chemistry Synthesis of 1,4-Disubstituted 1,2,3-Trivia a Copper(I)-Catalyzed Three-Component Reaction. — The fast and ef10- 134 azoles
ficient three-component reaction for generation of 1,4-disubstituted-1,2,3-triazoles in
a completely regioselective manner avoids isolation and handling of potentially unstable small organic azides and provides triazole products in a pure form. Product (Va),
otherwise difficult to prepare due to the hazardous nature of methyl azide, is obtained
in good yield. — (APPUKKUTTAN, P.; DEHAEN, W.; FOKIN*, V. V.; VAN DER
EYCKEN, E.; Org. Lett. 6 (2004) 23, 4223-4225; Dep. Chem., Scripps Res. Inst., San
Diego, La Jolla, CA 92037, USA; Eng.) — Steudel
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