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2005
Polyphenyl derivatives
Q 0700
Sterically Demanding, Bioxazoline-Derived N-Heterocyclic Carbene Ligands with
Flexibility for Catalysis. — The palladium complex derived in situ from
11- 107 Restricted
BIO is found to efficiently catalyze the Suzuki—Miyaura cross-coupling reaction of
sterically hindered aryl halides, and particularly chlorides, with hindered aryl boronic
acids. For the first time, tetraortho-substituted biaryls are obtained by this method. —
(ALTENHOFF, G.; GODDARD, R.; LEHMANN, C. W.; GLORIUS*, F.; J. Am.
Chem. Soc. 126 (2004) 46, 15195-15201; MPI Kohlenforsch.,
D-45470 Muelheim/Ruhr, Germany; Eng.) — Klein
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