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2005
Organo-silicon compounds
S 0060
Synthesis of Silyl Aziridines and α-Amino Acylsilanes with Silyldibromomethyllithium. — The reaction of substrate (I) with aromatic imines affords α-amino acylsi11- 170 lanes
after quenching. The reaction proceeds via a bromo aziridine intermediate, which
is efficiently alkylated upon treatment with Grignard reagents. In this case trisubstituted
silylated aziridines are obtained in good yields with high stereoselectivity. — (YAGI,
K.; SHINOKUBO*, H.; OSHIMA, K.; Org. Lett. 6 (2004) 23, 4339-4341; Dep.
Chem., Grad. Sch. Sci., Kyoto Univ., Sakyo, Kyoto 606, Japan; Eng.) — Steudel
2005
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