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2005
Rhenium
I 7000
12- 026
Synthesis and Crystal Structure of (PPh4)3[Re2NCl10]. — In the reaction of (I) with
1,3-dioxan-(2-ylmethyl)diphenylphosphine, the phosphine does not act as a ligand, but
apparently reduces ReVI to ReV resulting in the formation of the title compound. (II)
crystallizes in the triclinic space group P1 with Z = 2 (single crystal XRD). The crystal
structure contains two symmetry-independent, centrosymmetrical [Re2NCl10]3- complex anions having symmetrical Re=N=Re nitrido bridges with Re(1)—N(1) and
Re(2)—N(2) distances of 181.34 and 181.51 pm, respectively. — (SCHWARZ, S.;
STRAEHLE*, J.; Z. Anorg. Allg. Chem. 630 (2004) 15, 2717-2719; Inst. Anorg.
Chem., Eberhard-Karls-Univ., D-72076 Tuebingen, Germany; Ger., Abstr. Eng.) —
Schramke
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