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2005
C-C bond formation
O 0282
Phosphaadamantanes as Ligands for Palladium Catalyzed Cross-Coupling
Library Synthesis, Characterization, and Screening in the Suzuki
12- 057 Chemistry:
Coupling of Alkyl Halides and Tosylates Containing β-Hydrogens with Boronic
Acids and Alkylboranes. — A number of phosphaadamantanes like (I) are prepared
and tested as ligands in the Suzuki coupling. The most effective one is the derivative
(Ia) which facilitates the reaction of alkyl halides and tosylates containing β-hydrogens.
— (BRENSTRUM, T.; GERRISTMA, D. A.; ADJABENG, G. M.; FRAMPTON, C.
S.; BRITTEN, J.; ROBERTSON, A. J.; MCNULTY, J.; CAPRETTA*, A.; J. Org.
Chem. 69 (2004) 22, 7635-7639; Dep. Chem., McMaster Univ., Hamilton, Ont.
L8S 4M1, Can.; Eng.) — Jannicke
2005
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