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2005
Intercalation
H 2100
Chemical and Electrochemical Li-Insertion into the Li4Ti5O12 Spinel. — The
and electrochemical Li insertion into the title spinel is studied by 6,7Li NMR,
13- 021 chemical
Raman spectroscopy, XRD, and neutron diffraction. Chemically inserted Li ions are
trapped in the (48f) sites of the spinel structure from which they cannot be extracted by
electrochemical means. In contrast to the electrochemical Li insertion, which is
accompanied by a spinel to rocksalt phase transition, no such structural change occurs
for chemical insertion. — (ALDON*, L.; KUBIAK, P.; WOMES, M.; JUMAS, J. C.;
OLIVIER-FOURCADE, J.; TIRADO, J. L.; CORREDOR, J. I.; PEREZ VICENTE,
C.; Chem. Mater. 16 (2004) 26, 5721-5725; Lab. Agregats Mol. Materiaux Inorg.,
CNRS, Univ. Montpellier, F-34095 Montpellier, Fr.; Eng.) — W. Pewestorf
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