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2005
Organo-phosphorus compounds
S 0080
Fluoride-Mediated Phosphination of Alkenes and Alkynes by Silylphosphines.
A variety of alkenes and alkynes substituted with a directing group undergo fluo13- 185 —
ride-mediated reaction with the silylated phosphine (II) to yield β-adducts regioselectively. Under anhydrous conditions a three-component coupling can be realized with
benzaldehyde as the electrophile. — (HAYASHI*, M.; MATSUURA, Y.;
WATANABE, Y.; Tetrahedron Lett. 45 (2004) 50, 9167-9169; Dep. Appl. Chem., Fac.
Eng., Ehime Univ., Matsuyama, Ehime 790, Japan; Eng.) — Mais
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