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2005
Nucleic acids
U 0700
Pd-Catalyzed Amination of Nucleoside Arylsulfonates to Yield N6-Aryl-2,6-diaminopurine Nucleosides. — Under optimized reaction conditions a number of elec13- 225 tron-rich,
electron-deficient as well as sterically congested aromatic amines are coupled
with the arylsulfonate derivative of 2-deoxyguanosine. The interplay between the nature of the ligand, the substituent on the arylsulfonate, as well as the type of reaction
that is conducted are studied. — (GUNDA, P.; RUSSON, L. M.; LAKSHMAN*, M.
K.; Angew. Chem., Int. Ed. 43 (2004) 46, 6372-6377; Dep. Chem., City Coll., City
Univ., New York, NY 10031, USA; Eng.) — Bartels
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