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2005
Ring closure reactions
O 0130
Palladium-Catalyzed Intramolecular α-Arylation of Aliphatic Ketone, Formyl,
Nitro Groups. — By use of Cs2CO3 and catalytic amounts of PdCl2(PPh3)2, a va14- 042 and
riety of carbocyclic compounds are formed by intramolecular arylation of properly designed precursors bearing a keto, formyl, or nitro group. For each of the three types of
compounds different products are obtained, depending on the position of the functional
groups. — (MURATAKE*, H.; NATSUME, M.; NAKAI, H.; Tetrahedron 60 (2004)
51, 11783-11803; Res. Found. Itsuu Lab., Setagaya, Tokyo 158, Japan; Eng.) —
Klein
2005
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