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2005
Amines
P 0060
14- 067
Reaction of Organic Compounds with a System SF4—HF—Halogenating Agent.
Part 15. Reactions of Aliphatic Nitriles with SF4—HF—Cl 2(S2Cl 2). — The reactions of acetonitrile, halogenated aliphatic nitriles, and a perfluorodinitrile with the two
title systems are studied. For hydrogen-containing nitriles besides the addition/isomerization reaction of SF4 across the nitrile triple bond, a replacement of hydrogen atoms
by chlorine or fluorine occurs. (Ratios of reagents are given in g). —
(KUNSHENKO, B. V.; MOTORNAYA, L. V.; YAGUPOL'SKII, L. M.; Russ. J. Org.
Chem. 39 (2003) 8, 1064-1068; Odessa Natl. Polytech. Univ., Odessa 65044, Ukraine;
Eng.) — Klein
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