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2005
Carboxylic amides
P 0320
Stereoselective Preparation of α-Hydroxycarboxamide by Manganese Complex
Hydration of α,β-Unsaturated Carboxamide with Molecular Oxygen
14- 070 Catalyzed
and Phenylsilane. — The title reaction is successfully applied to α,β-unsaturated carboxamides (I), (III) and (V) containing various chiral auxiliaries. The corresponding
α-hydroxycarboxamides (II), (IV) and (VI) are obtained in good yield and stereoselectivity. — (SATO, M.; GUNJI, Y.; IKENO, T.; YAMADA*, T.; Chem. Lett. 33 (2004)
10, 1304-1305; Dep. Chem., Fac. Sci. Technol., Keio Univ., Kohoku, Yokohama 223,
Japan; Eng.) — M. Paetzel
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