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2005
Polyphenyl derivatives
Q 0700
Fluorous-Silica-Supported Perfluoro-Tagged Palladium Complexes Catalyze
Couplings in Water. — Perfluoro-tagged palladium complexes immobilized
14- 094 Suzuki
on fluorous reversed-phase silica gel are used as precatalysts for Suzuki coupling reactions in water. A wide range of water-soluble substrates are converted into the corresponding biphenyls. With low catalyst loadings, TON's up to 200,000 are achieved.
— (TZSCHUCKE, C.; BANNWARTH*, W.; Helv. Chim. Acta 87 (2004) 11,
2882-2889; Inst. Org. Chem. Biochem., Albert-Ludwigs-Univ., D-79104 Freiburg/Br.,
Germany; Eng.) — S. Adam
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