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2005
Fused pyridine derivatives
R 0450
Microwave-Accelerated Pictet—Spengler Reactions of Tryptophan with Ketones
Toward the Preparation of 1,1-Disubstituted Indole Alkaloids. — It is
14- 160 Directed
found that slow Pictet—Spengler reactions of tryptophan and its methyl ester with
ketones can be significantly accelerated (from days to minutes) using microwave irradiation. Thus, a practical, fast, and efficient route to carboline derivatives and indole
alkaloids is opened. — (KUO, F.-M.; TSENG, M.-C.; YEN, Y.-H.; CHU*, Y.-H.;
Tetrahedron 60 (2004) 52, 12075-12084; Dep. Chem. Biochem., Natl. Chung Cheng
Univ., Chia-Yi 621, Taiwan; Eng.) — Jannicke
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