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2005
Pyrimidine derivatives
R 0510
Pyrimidine-Core Extended π-Systems: General Synthesis and Interesting FluoProperties. — On the basis of iterative additions of aryllithiums to 2-methyl14- 162 rescent
thiopyrimidine (I), various electronically diverse aryl groups are assembled onto the
pyrimidine and 2,2'-bipyrimidine core in a programmable and diversity-orientated
manner. Products such as (VI), (X), (XI) or (XIV) are obtained. A number of interesting
fluorescent properties (e.g. solvatofluorochromism) are detected. — (ITAMI*, K.;
YAMAZAKI, D.; YOSHIDA, J.-I.; J. Am. Chem. Soc. 126 (2004) 47, 15396-15397;
Dep. Synth. Chem. Biol. Chem., Grad. Sch. Eng., Kyoto Univ., Nishikyo, Kyoto 615,
Japan; Eng.) — Kieslich
2005
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