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2005
Sorption
G 6000
15- 021
Hydrogen Desorption Exceeding Ten Weight Percent from the New Quaternary
Hydride Li3BN 2H8. — The title compound is synthesized by reacting LiNH2 and
LiBH4 powders in a 2:1 molar ratio either by ball milling or by heating the mixed powders above 95 °C. The samples are characterized by powder XRD. The compound releases ≥10 wt% H2 above approximately 250 °C together with a small amount of NH3.
The title compound exemplifies a promising new class of hydride materials with significant hydrogen storage potential for stationary and mobile applications. —
(PINKERTON*, F. E.; MEISNER, G. P.; MEYER, M. S.; BALOGH, M. P.;
KUNDRAT, M. D.; J. Phys. Chem. B 109 (2005) 1, 6-8; Mater. Process. Lab.,
General Motors Res. Dev. Cent., Warren, MI 48090, USA; Eng.) — W. Pewestorf
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