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2005
Peptides
U 0400
15- 178
Chemical Mediators: The Remarkable Structure and Host-Selectivity of Depsilairdin, a Sesquiterpenic Depsipeptide Containing a New Amino Acid. — The
structure assignment of the title compound is carried out using NMR and X-ray analysis. (I) is found to cause strong necrotic and chlorotic lesions only on brown mustard
leaves, whereas no damage is observed on canola or white mustard leaves. The high
selectivity of (I) appears to mimic the pathogenicity range of the producing isolates,
and the lesions resemble the disease symptoms, which is consistent with a chemically
mediated interplay between host and pathogen. — (PEDRAS*, M. S. C.; CHUMALA,
P. B.; QUAIL, J. W.; Org. Lett. 6 (2004) 24, 4615-4617; Dep. Chem., Univ.
Saskatchewan, Saskatoon, Sask. S7N 5C9, Can.; Eng.) — Steudel
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