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2005
Microbiological syntheses
O 0035
Highly Compatible Metal and Enzyme Catalysts for Efficient Dynamic Kinetic
of Alcohols at Ambient Temperature. — The present dynamic kinetic
16- 033 Resolution
resolution of secondary alcohols provides enantiopure products in comparatively short
reaction times. In every case the mixture of Ru complex and KOtBu must be stirred for
6 minutes in toluene to activate the catalyst. For first time, enantiopure products (IIId,e)
are successfully obtained. — (MARTIN-MATUTE, B.; EDIN, M.; BOGAR, K.;
BAECKVALL*, J.-E.; Angew. Chem., Int. Ed. 43 (2004) 47, 6535-6539; Dep. Org.
Chem., Arrhenius Lab., Univ. Stockholm, S-106 91 Stockholm, Swed.; Eng.) —
S. Adam
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