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2005
Lipids
U 0750
16- 186
Synthesis of First Phospholipids from 2,2,6,6-Tetrakis(hydroxymethyl)cyclohexanol. — New phospholipid systems containing a carbocyclic polyol fragment are synthesized. Compound (VIII) is synthesized as a model of terminal choline thio phospholipid. Apart from phosphocholine derivative (VIII), thiophosphate (VI) is used to prepare the model diol phospholipid (X). Reaction of acetal (III) with further phosphorus-containing heterocyclic compounds afford cationic ammonium amidophosphorus
lipid models (e.g. cholesterol phospholipid). — (PREDVODITELEV, D. A.; SAVIN,
G. A.; MALENKOVSKAYA, M. A.; NIFANT'EV, E. E.; Russ. J. Org. Chem. 40
(2004) 9, 1364-1370; Moscow Pedagog. State Univ., Moscow 119021, Russia; Eng.)
— H. Hoennerscheid
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