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2005
Enzyme inhibiting activity
X 0220
Cyclen-Containing Inhibitors of Carboxypeptidase A Synthesized in Search of
Artificial Proteases. — Eight title compounds of type (I) or (II) are
16- 224 Target-Selective
prepared as diastereomeric mixtures which can be separated by HPLC. The Cu(II) and
Co(III) complexes of the isomers of (I) and (II) with the longer elution time contain an
effective binding site for carboxypeptidase A (CPA) as well as the peptide-cleaving catalytic center, but they fail to cleave the peptide backbone of CPA. — (SONG, J. B.;
HAH, S. S.; SUH*, J.; Bull. Korean Chem. Soc. 25 (2004) 11, 1703-1706; Sch.
Chem., Seoul Natl. Univ., Seoul 151-747, S. Korea; Eng.) — M. Bohle
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