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200517.fm Page 35 Friday, March 18, 2005 2:52 PM
2005
Enantioselective syntheses
O 0031
Stereocontrolled Creation of Adjacent Quaternary and Tertiary Stereocenters by
Catalytic Conjugate Addition. — A highly diastereo- and enantioselective catalytic
17- 035 aconjugate
addition is presented as an efficient method for the stereocontrolled construction of adjacent carbon- or heteroatom-substituted quaternary and tertiary stereocenters. A wide range of substituents is accepted in both Michael acceptors and Michael
donors. — (LI, H.; WANG, Y.; TANG, L.; WU, F.; LIU, X.; GUO, C.; FOXMAN, B.
M.; DENG*, L.; Angew. Chem., Int. Ed. 44 (2005) 1, 105-108; Dep. Chem., Brandeis
Univ., Waltham, MA 02454, USA; Eng.) — Mischke
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