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200517.fm Page 38 Friday, March 18, 2005 2:52 PM
2005
Addition reactions
O 0060
Oxidative Addition of N-Aminophthalimide and 3-Amino-2-methylquinazoto Conjugated Azocyclopentenes and Azocyclohexenes. — The oxi17- 038 lin-4(3H)-one
dative addition of N-aminophthalimide (II) to azocyclohexenes (I) leads to bicyclic
aziridine adducts (III) irrespective of the structure of (I). However, the direction in the
reaction of (IV) and (VII) with 2-methylquinolin-4(3H)-one (V) depends on the structure of the azo-compounds to afford either azoaziridines (VI) or bicyclic triazoles
(VIII). — (BUCHAKA*, S. M.; KUZNETSOV, M. A.; SCHANTL, J. G.; Chem.
Heterocycl. Compd. (N. Y.) 40 (2004) 7, 895-902; St. Petersburg State Univ.,
St. Petersburg 198904, Russia; Eng.) — R. Staver
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