close

Вход

Забыли?

вход по аккаунту

?

код для вставки
200517.fm Page 62 Friday, March 18, 2005 2:52 PM
2005
C-C bond formation
O 0282
An Improved Protocol for the Synthesis of Allylated Isonitriles. — The reaction of
(I) with allylic carbonates, benzoates and phosphates is investigated. Best
17- 059 isonitrile
results are obtained by use of Cs2CO3 as base to deprotonate the isonitrile, and dppe as
ligand. For acyclic allylic partners, carbonate is the leaving group of choice, whereas
for cyclic allylic substrates, the phosphate group is more suitable. — (KAZMAIER*,
U.; ACKERMANN, S.; Synlett 2004, 14, 2576-2578; Inst. Org. Chem., Univ. des
Saarlandes, D-66123 Saarbruecken, Germany; Eng.) — Klein
Документ
Категория
Без категории
Просмотров
0
Размер файла
25 Кб
Теги
1/--страниц
Пожаловаться на содержимое документа