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200517.fm Page 77 Friday, March 18, 2005 2:52 PM
2005
Cyclopropane derivatives
Q 0021
Synthesis of Stereohomogeneous Cyclopropanecarbaldehydes and Cyclopropyl
by Cycloalkylation of 4-Hydroxy-1-alkenyl Carbamates. — Two methods
17- 074 Ketones
for transformation of readily available title compounds into cyclopropane derivatives
are presented in continuation of previously published studies. The products are
obtained without changes in optical purity. — (KALKOFEN, R.; BRANDAU, S.;
WIBBELING, B.; HOPPE*, D.; Angew. Chem., Int. Ed. 43 (2004) 48, 6667-6669;
Org.-Chem. Inst., Westfael. Wilhelms Univ., D-48149 Muenster, Germany; Eng.) —
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