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200517.fm Page 91 Friday, March 18, 2005 2:52 PM
2005
Carboxylic acids
Q 0420
Synthesis of 1,4:3,6-Dianhydro-D-mannitol 2,5-(Hydrogen phosphate) and Its
in Palladium-Catalyzed Hydroxycarbonylation of Styrene. — A cyclic
17- 087 Usage
hydrogen phosphate is prepared and applied as the catalyst ligand in the title reaction.
The regioselectivity is good, since the linear acids (IV) are formed in only a few percents. However, the stereoselectivity is poor. — (JIANG*, B.; HUANG, Z.-G.;
CHENG, K.-J.; Heterocycles 63 (2004) 12, 2797-2803; State Key Lab. Organomet.
Chem., Shanghai Inst. Org. Chem., Chin. Acad. Sci., Shanghai 200032,
Peop. Rep. China; Eng.) — Mais
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