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200517.fm Page 190 Friday, March 18, 2005 2:52 PM
2005
Triazine derivatives
R 0655
A General Approach to Selective Functionalization of 1,2,4-Triazines Using
in Palladium-Catalyzed Cross-Coupling and Addition Reac17- 171 Organometallics
tions. — The selectivity concerning the reactions of 3-methylsulfanyl-1,2,4-triazine (I)
with organo-metal reagents or in Pd-catalyzed cross-coupling reactions is examined in
detail. The findings result in strategies towards the selective synthesis of 3,5-disubstituted 1,2,4-triazines. — (ALPHONSE, F.-A.; SUZENET, F.; KEROMNES, A.;
LEBRET, B.; GUILLAUMET*, G.; Synthesis 2004, 17, 2893-2899; Inst. Chim. Org.
Anal., CNRS, Fac. Sci., Univ. Orleans, F-45067 Orleans, Fr.; Eng.) — Mais
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