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2005
Deprotection
O 0345
Facile and Chemoselective Microwave-Assisted Cleavage of Oximes to Their
Carbonyl Compounds Using N,N'-Dibromo-N,N'-1,3-propy18- 056 Corresponding
lene-bis[(4-methylphenyl)sulfonamide] as a Deoximating Reagent. — A novel
N,N-dibromo-bis-tosylamide is presented as reagent for the efficient cleavage of
oximes to the corresponding carbonyl compounds. The oxidative deprotection can be
selectively achieved in the presence of oxidizable functionalities such as alcohols and
alkenes. — (KHAZAEI*, A.; MANESH, A. A.; GHASEMI, A. H.; Synthesis 2004,
17, 2784-2786; Dep. Chem., Coll. Sci., Univ. Bu-Ali Sina, Hamadan 65174, Iran;
Eng.) — Mais
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