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2005
Theory
C 1000
19- 003
Violation of the Isolated Square Rule for Group 13—15 Oligomers: Theoretical
Prediction of a New Class of Inorganic Polymers. — DFT calculations for
[RMYR]n (M: B, Al, Ga, In; Y: N, P, As) oligomers indicate that needle-shaped pnictidometallanes with high oligomerization degree possess greater stability than cage
structures and that the generation of gas phase [HMYH]n oligomers is thermodynamically very favorable. The synthesis of novel inorganic polymers formed by fusion of
trimeric M3Y3 rings is expected to be possible. — (TIMOSHKIN*, A. Y.;
SCHAEFER, H. F. I.; Inorg. Chem. 44 (2005) 4, 843-845; Dep. Chem., St. Petersburg
State Univ., St. Petersburg 198904, Russia; Eng.) — Schramke
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