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2005
Structure
D 2000
19- 006
Structure and Bonding of Li1.42(5)Pd2Sn5.58(5): A Lithium Intercalated Palladium
Stannide. — The title compound is prepared from the elements by induction melting.
The samples are characterized by powder and single crystal XRD, and first principles
electronic structure calculations in the framework of the frozen core all-electron projected augmented wave method. The compound crystallizes in the space group P4/mbm
with Z = 4. The Pd atoms have a square antiprismatic Sn coordination. The square
antiprisms are condensed via common edges and faces forming [Pd2Sn6] double layers
in a simple stacking sequence which leaves square prismatic voids for the Li atoms.
— (SREERAJ, P.; HOFFMANN, R.-D.; WU, Z.; POETTGEN*, R.;
HAEUSSERMANN, U.; Chem. Mater. 17 (2005) 4, 911-915; Inst. Anorg. Anal.
Chem., Westfael. Wilhelms-Univ., D-48149 Muenster, Germany; Eng.) —
W. Pewestorf
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