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2005
Thermochemistry
E 3000
Thermochemical Properties of the Gaseous Bromo-Iodides of Dy and of the
Tetrahalo Complexes. — The gaseous species NaDyBr4, NaDyI4, DyBrI,
19- 013 Na—Dy
DyBr2I, DyBrI2, NaDyBr3I, NaDyBr2I2, and NaDyBrI3 are generated in an effusion cell
reactor at elevated temperatures and characterized by mass spectrometry. Thermodynamic data for a number of gaseous equilibria involving these species are given. Salt
mixtures in both the Na—Dy—Br and Na—Dy—I systems are used in metal halide
lamps because of the favorable color renditions associated with the two metal emitters
under lamp operating conditions. — (HILDENBRAND*, D. L.; LAU, K. H.;
BAGLIO, J. W.; STRUCK, C. W.; J. Phys. Chem. A 109 (2005) 7, 1481-1486; SRI
Int., Menlo Park, CA 94025, USA; Eng.) — W. Pewestorf
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