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2005
Rearrangements
O 0140
Stereoselective Synthesis of 1,2,3-Trisubstituted 1,3-Dienes Through Novel
Rearrangements in α-Allenic Methanesulfonates: Application
19- 049 [3,3]-Sigmatropic
to the Preparation of Fused Tricyclic Systems by Tandem Rearrangement/
Diels—Alder Reaction. — The α-allenols used as starting materials in the title investigation are readily prepared by a indium-mediated Barbier-type allenylation of the corresponding aldehydes (to be continued). — (ALCAIDE*, B.; ALMENDROS, P.;
ARAGONCILLO, C.; REDONDO, M. C.; Eur. J. Org. Chem. 2005, 1, 98-pp; Dep.
Quim. Org., Fac. Quim., Univ. Complutense, E-28040 Madrid, Spain; Eng.) —
Nuesgen
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