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2005
Halogen compounds
P 0030
A Direct Approach to α-Hydroxy and α-Chloro Trifluoromethyl Derivatives. —
dithiocarbonates react efficiently with various olefins in the presence of
19- 071 Fluorinated
small amounts of lauroyl peroxide to afford diastereomeric mixtures of adducts (III),
(VIII) and (XI). Additionally, a number of further transformations is described to get
products of pharmaceutical interest. — (TOURNIER, L.; ZARD*, S. Z.; Tetrahedron
Lett. 46 (2005) 3, 455-459; Lab. Synth. Org., CNRS, DCSO, Ec. Polytech.,
F-91128 Palaiseau, Fr.; Eng.) — Mais
2005
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