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2005
Fused pyridine derivatives
R 0450
Stereoselective Synthesis of 1-Substituted 1,2,3,4-Tetrahydro-β-carbolines by
Electrophilic α-Amidoalkylation Reactions. — Based on the stereose19- 170 Asymmetric
lective addition of organometallic reagents to the chiral N-acyl-β-carbolinium substrate
(II), an asymmetric synthesis of the title compounds (VII) is described. The in vitro
activity of the phenyl substituted derivative (VIId) on the PCP binding site of the
NMDA receptor is determined. — (WEBER, U.; HOESL, C.; PONIKWAR, W.;
SUTER, M.; NOETH, H.; WANNER*, K. T.; Heterocycles 63 (2004) 12, 2747-2767;
Inst. Pharm., Ludwig-Maximilians-Univ., D-81377 Muenchen, Germany; Eng.) —
Mais
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