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2005
Superconductors
D 8000
Ba4Mo 12S18: A Superconductor Containing the Dimeric Unit (Mo6)2S24 , the MissLink Between the Mo6S14 and Mo9S17 Units. — The title compound is synthe20- 010 ing
sized from a stoichiometric mixture of MoS2, BaS, and Mo (1500 °C, 4 d). Ba 4Mo 12S18
crystallizes in the hexagonal space group P63/mmc with Z = 2 as revealed by single
crystal XRD. Single crystal electrical resistivity measurements indicate that the compound is poorly metallic, with a room temperature resistivity of around 1 mΩcm, and
becomes a superconductor below 7 K. — (SALLOUM, D.; GAUTIER, R.; POTEL,
M.; GOUGEON*, P.; Angew. Chem., Int. Ed. 44 (2005) 9, 1363-1365; Inst. Chim.,
CNRS, Univ. Rennes, F-35042 Rennes, Fr.; Eng.) — W. Pewestorf
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