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2005
Alkenes
P 0023
20- 055
Enantioselective Copper-Mediated Allylic Substitution with Grignard Reagents
Employing a Chiral Reagent-Directing Leaving Group. — Cu-mediated treatment
of the ferrocene esters with aliphatic Grignard reagents allows highly regio- and enantioselective formation of allylic products. The geometry of C=C double bond and the
solvent as well as concentration and addition time of the Grignard reagent play an important role on the reaction outcome. — (BREIT*, B.; BREUNINGER, D.; Synthesis
2005, 1, 147-157; Inst. Org. Chem. Biochem., Albert-Ludwigs-Univ., D-79104
Freiburg/Br., Germany; Eng.) — Jannicke
2005
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