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2005
Nitro compounds
P 0040
NaNO2-Mediated Transformation of Aliphatic Secondary Nitroalkanes into Keor Oximes under Neutral, Aqueous Conditions: How the Nitro Derivative
20- 056 tones
Catalyzes Its Own Transformation. — The procedure offers a new, mild, and efficient method to prepare ketones or oximes. The nature of the nitro compound has a
strong effect on the reaction outcome. Nitrosated species are generated in situ which
catalyze the conversion into ketones or oximes. — (GISSOT, A.; N'GOUELA, S.;
MATT, C.; WAGNER*, A.; MIOSKOWSKI, C.; J. Org. Chem. 69 (2004) 26,
8997-9001; Lab. Synth. Bio-Org., CNRS, Fac. Pharm., Univ. Louis Pasteur, F-67401
Illkirch, Fr.; Eng.) — Jannicke
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