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2005
Polyphenylalkane derivatives
Q 0720
Three-Component Reaction of Aryl Diazoacetates, Alcohols, and Aldehydes (or
Evidence of Alcoholic Oxonium Ylide Intermediates. — The first exam20- 086 Imines):
ple of Rh(II)-catalyzed three-component reactions of aryl diazoacetates, alcohols, and
aldehydes/imines is described. The intermediate oxonium ylide is trapped with formation of the new C—C bond. When diazoacetate (I) is used as substrate, significant
amounts of insertion products (IX) are obtained in some cases. — (LU, C.-D.; LIU,
H.; CHEN, Z.-Y.; HU*, W.-H.; MI, A.-Q.; Org. Lett. 7 (2005) 1, 83-86; Chengdu
Inst. Org. Chem., Chin. Acad. Sci., Chengdu 610041, Peop. Rep. China; Eng.) —
Steudel
2005
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