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2005
Benzofuran derivatives
R 0070
Sequential Homobimetallic Catalysis: An Unprecedented Tandem Pd(0)-CataDeprotection — Pd(II)-Catalyzed Heterocyclization Reaction Leading to
20- 107 lyzed
Benzofurans. — An unprecedented catalytic sequence involving two sequential catalytic cycles leading to benzofurans (IV) is reported. In the first cycle, promoted by
Pd(0), deprotection of a nucleophilic oxygen occurs with formation of the substrate undergoing the subsequent carbonylative heterocyclization process catalyzed by Pd(II).
— (GABRIELE*, B.; MANCUSO, R.; SALERNO, G.; VELTRI, L.; Chem.
Commun. (Cambridge) 2005, 2, 271-273; Dip. Sci. Farm., Univ. Calabria, I-87030
Arcavacata di Rende, Cosenza, Italy; Eng.) — M. Paetzel
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