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2005
Radical reactions
O 0195
Dimethylzinc-Initiated Radical Reaction of Cyclic Ethers with Arylamines,
and Dialkylhydrazines. — In the presence of dimethylzinc/air, cyclic
21- 049 Alkoxyamines,
ethers and alkoxyamines afford oximes of ω-hydroxyalkanals. By treatment of hydrazines in place of alkoxyamines under the same conditions, the corresponding hydrazones are formed. Arylamines and THF give amino alcohols (III) by reaction of two
molecules of THF (IIb) and one molecule of arylamine. — (YAMAMOTO, Y.;
MAEKAWA, M.; AKINDELE, T.; YAMADA, K.-I.; TOMIOKA*, K.; Tetrahedron
61 (2005) 2, 379-384; Grad. Sch. Pharm. Sci., Kyoto Univ., Sakyo, Kyoto 606, Japan;
Eng.) — Klein
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