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2005
Organo-selenium compounds
S 0130
α-Phenylselanyl Imines: Preparation of β-Phenylselanyl Amines and Original
of Allylaziridines. — By application of suitable methods, a wide variety of
21- 182 Synthesis
phenylselanyl aldehydes and ketones can be converted into the corresponding imines
which are subsequently reduced to afford phenylselanyl amines. The imines are isolated and characterized by NMR and IR data, but not purified due to decomposition. The
undesired formation of deselenylated amines during reduction of the imines is completely avoided by use of NaBH3CN/AcOH as reducing agent (to be continued). —
(MINIEJEW, C.; OUTURQUIN*, F.; PANNECOUCKE, X.; Tetrahedron 61 (2005) 2,
447-pp; Inst. Rech. Chim. Org. Fine, CNRS, Inst. Natl. Sci. Appl. Rouen,
F-76131 Mont-Saint-Aignan, Fr.; Eng.) — Klein
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