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2005
Amino acids
U 0400
Novel α-Functionally Substituted Amino Acids: Diphenylphosphinoglycines. —
three-component one-pot reaction of glyoxalic acid hydrate with P-H and N-H
21- 195 The
compounds allows a convenient access to phosphinoglycines. The molecular structure
of (VII), some reactions and an alternative formation of bis(glycolate) (IV) is reported.
Furthermore, it is found that compound (VII) decarboxylates quickly in THF and particularly in CDCl3 solution (no yields given). — (HEINICKE*, J.; PEULECKE, N.;
JONES, P. G.; Chem. Commun. (Cambridge) 2005, 2, 262-264; Inst. Chem.
Biochem., Ernst-Moritz-Arndt-Univ., D-17487 Greifswald, Germany; Eng.) —
M. Paetzel
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