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2005
Hydrogenated naphthalene derivatives
Q 1010
Reductive Intramolecular Henry Reactions Induced by Stryker's Reagent. —
alcohols are synthesized by conjugate reduction of nitroalkenes using Stryker's
22- 085 β-Nitro
reagent followed by intramolecular aldol reaction. The present reactions are the first
examples of reductive Henry reactions. Nitro alcohol (XIII) is transformed into
α-hydroxyketone (XV) by Nef reaction with a concomitant retro-aldol reaction. —
(CHUNG, W. K.; CHIU*, P.; Synlett 2005, 1, 55-58; Dep. Chem., Univ. Hong Kong,
Kowloon, Hong Kong, Peop. Rep. China; Eng.) — S. Adam
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