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2005
Other polycyclic compounds
Q 1150
A Soluble Pentacene: Synthesis, EPR and Electrochemical Studies of
— A soluble pentacene (II) is synthe22- 092 2,3,9,10-Tetrakis(trimethylsilyl)pentacene.
sized according to the scheme. Furthermore, to support the structure of (II) the synthesis
of some Diels-Alder adducts, e.g. (VI) and (VIII), is performed. The discovery of the
radical cationic character of (II) in solution through EPR measurement provides insights into the sensitivity of acenes towards light and oxygen. — (CHAN, S. H.; LEE,
H. K.; WANG, Y. M.; FU, N. Y.; CHEN, X. M.; CAI, Z. W.; WONG*, H. N. C.;
Chem. Commun. (Cambridge) 2005, 1, 66-68; Dep. Chem., Chin. Univ. Hong Kong,
Shatin, Hong Kong, Peop. Rep. China; Eng.) — M. Paetzel
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