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2005
Oxirane derivatives
R 0030
A Dynamic Supramolecular System Exhibiting Substrate Selectivity in the CataEpoxidation of Olefins. — A dynamic supramolecular system involving bond22- 093 lytic
ing between a Mn(III) salen catalyst and a Zn(II) porphyrin receptor for the catalytic
epoxidation reaction is described. In competitive reactions this catalyst system exhibits
selectivity for pyridine appended cis-β-substituted styrene derivatives, such as (Ib) and
(Ic) over the corresponding phenyl analogues (Ia). — (JONSSON, S.; ODILLE, F. G.
J.; NORRBY, P.-O.; WAERNMARK*, K.; Chem. Commun. (Cambridge) 2005, 4,
549-551; Dep. Chem., Lund Univ., S-221 00 Lund, Swed.; Eng.) — M. Paetzel
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