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2005
Fused pyrrole derivatives
R 0160
Zinc Mediated Barbier Type Allylation of Cyclic Imides and Subsequent Coupling
with Carbon Nucleophiles. — The effect of different conditions (temper22- 112 Reactions
ature, solvent, catalyst) on the title reaction is studied. Subsequent coupling reactions
with carbon nucleophiles afford 1,2- and 1,4 addition products such as (X) and (XII)
whereas Diels—Alder products, cf. (XIII), are obtained on heating in AcOH. —
(KANG, S. W.; HEO, E. Y.; JUN, J. G.; KIM*, S. H.; Bull. Korean Chem. Soc. 25
(2004) 12, 1924-1928; Dep. Chem., Kon-Kuk Univ., Kwangjinku, Seoul 143-701,
S. Korea; Eng.) — H. Haber
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