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2005
Pyrimidine derivatives
R 0510
Efficient Synthesis of Various Acycloalkenyl Derivatives of Pyrimidine Using
and Pd(0) Methodologies. — The synthesis of new acycloalkenyl
22- 159 Cross-Metathesis
pyrimidine nucleosides using Tsuji—Trost conditions for allylic N-alkylation, cross-metathesis reaction for modifying the acycloalkenyl substituent and Suzuki—Miyaura
reaction for introduction of C-5 substituents is reported. Few nucleoside analogues like
compounds (XIIIa) and (XIIIb) exhibit moderate anti-HIV and anti-HSV activity. —
(AMBLARD, F.; NOLAN, S. P.; SCHINAZI, R. F.; AGROFOGLIO*, L. A.;
Tetrahedron 61 (2005) 3, 537-544; Inst. Chim. Org. Anal., CNRS, Fac. Sci., Univ.
Orleans, F-45067 Orleans, Fr.; Eng.) — Bartels
2005
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