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2005
Nucleic acids
U 0700
Stereoselective Synthesis and Antiviral Activity of Novel 4'(α)-Hydroxymethyl
6'(α)-Methyl Dually Branched Carbocyclic Nucleosides. — A novel synthetic
22- 202 and
method for branched carbocyclic nucleosides (XIII) and (XV) is reported. The bis-vinyl
intermediate (VII) is cyclized using Grubbs' II catalyst. Adenine and cytosine are coupled via a Pd(0)-catalyzed reaction. The resulting nucleosides are screened for their antiviral activity and it is found that (XV) shows good activity against HCMV. — (KIM,
J. W.; CHOI, B. G.; HONG*, J. H.; Bull. Korean Chem. Soc. 25 (2004) 12, 1812-1816;
Coll. Pharm., Chosun Univ., Kwangju 501-759, S. Korea; Eng.) — H. Haber
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