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2005
Structure
C 1000
24- 001
Long-Lived Light-Induced Metastable States in
trans-[Ru(NH3)4(H2O)NO]Cl3·H 2O and Related Compounds. — The existence
of two light-induced long-lived metastable states in the irradiated title compound and
trans-[Ru(NH3)4(OH)NO]Cl2 is revealed by DSC measurements and DFT calculations.
The population and transfer behavior of the metastable states is described. The metastable states correspond to a side-on bonded and isonitrosyl configuration of the NO
ligand, respectively. The calculations provide the energetic minima of the ground state
and the metastable states as well as the saddle points along the reaction coordinate. —
(SCHANIEL*, D.; WOIKE, T.; DELLEY, B.; BOSKOVIC, C.; BINER, D.;
KRAEMER, K. W.; GUEDEL, H.-U.; Phys. Chem. Chem. Phys. 7 (2005) 6,
1164-1170; Inst. Min. Geochem., Univ. Koeln, D-50674 Koeln, Germany; Eng.) —
W. Pewestorf
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