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2005
Alcohols
Q 0230
24- 081
Lithium Acetate-Catalyzed Trifluoromethylation of Carbonyl Compounds with
(Trifluoromethyl)trimethylsilane. — Trifluoromethylation of various aldehydes and
ketones with silane (II) in the presence of a catalytic amount of a Lewis base such as
lithium acetate proceeds smoothly to afford the corresponding trifluoromethylated adducts. The influence of different reaction conditions is studied. — (MUKAIYAMA*,
T.; KAWANO, Y.; FUJISAWA, H.; Chem. Lett. 34 (2005) 1, 88-89; Cent. Basic Res.,
Kitasato Inst., Kita, Tokyo 114, Japan; Eng.) — H. Haber
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